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Quality Assurance

Measurements of any type contain a certain amount of error. This error component may be introduced when samples are collected, transported, stored, and analyzed or when data are stored or transferred electronically. It is the responsibility of quality assurance programs to provide a framework for determining and minimizing these errors through each step of the sample collection, analysis, and data management processes. The quality assurance programs for NTN ensure that samples are of high quality.  These programs are cooperative, interagency efforts with expertise and funding provided by the USGS, EPA, NADP/Central Analytical Laboratory, and the NADP Program Office.

NADP Quality Assurance Activities

INTER-NETWORK COMPARABILITY - National Trends Network and Canadian Air and Precipitation Monitoring Network (CAPMoN) stations are co-located at a site in Quebec, Canada, and a site in Pennsylvania, U.S.

INTER-LABORATORY COMPARABILITY - Analytical laboratories participate in interlaboratory proficiency tests to assess biases and variability of analytical data.

NETWORK PRECISION - Precipitation chemistry collectors and precipitation gages are operated side-by-side to determine overall precision.

NETWORK BIAS - Samples of known composition are sent to field site operators who transfer them to sample bottles and send them, disguised as precipitation samples, to the laboratory for (double-blind) analysis. Samples of known composition are sent to field site operators who transfer them to sample collection buckets after a dry sampling period. These buckets are handled and measured as if precipitation had occurred, and the samples are sent to the laboratory for (single-blind) analysis.

LABORATORY PRECISION - Samples are split, re-identified, and sent for (double-blind) analysis.

LABORATORY BIAS - Samples of known composition are sent for (double-blind) analysis by the laboratory QA officer.

LABORATORY QUALITY CONTROL - Standard laboratory practice includes frequent analysis of reagent and procedural blanks, instrument calibration check standards, control charts, random reanalysis, targeted reanalysis based on ion balance calculations, and numerous other internal controls.

LABORATORY PERFORMANCE REVIEWS – Periodic analytical laboratory performance reviews by a team of peer scientists.

FIELD CHEMISTRY ACCURACY - Samples of known composition are sent to all field site operators for (single-blind) pH and solution conductance measurements.

FIELD SITE PERFORMANCE REVIEWS – Biennial field site visits to test equipment operation, site operator performance, and adherence to site installation rules.

DATA VERIFICATION & SCREENING - Data quality are ensured through rigorous review, verification, and sample validation coding of field and laboratory data.

CAL Quality Assurance Reports

The free Acrobat Reader is required to read these Reports.

Earlier reports are available in print version by contacting the NADP Program Office.

Other Quality Assurance Documents

2008 Central Analytical Laboratory Quality Assurance Plan

Central Analytical Laboratory Standard Operating Procedures

List of QA/QC Glossary Terms and Equations

Table of Student's t Values

See also  http://nadp.sws.uiuc.edu/QA/

More information is available from publications at this site: http://bqs.usgs.gov/precip/project_overview/index.htm
                             

Web page was updated 08/20/2008

 

CAL Questions? Contact Chris Lehmann, Director
Central Analytical Laboratory - (217) 244-0868
Web Comments: E-Mail Pamela Bedient